Chitosan-grafted graphene oxide-reinforced bio-based waterborne epoxy nanocomposites for antibacterial and corrosion resistance in tropical marine environments: a mini-review
发布时间:2026-03-21点击次数:
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DOI码:10.3390/polym17212964
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发表刊物:Polymers
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关键字:Chitosan;Graphene oxide;Nanocomposite materials;Corrosion resistance;Coatings industry;Marine ecology;Antibacterial agents;Epoxy resins
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摘要:Epoxy resin coatings are widely employed for steel protection owing to their excellent adhesion, chemical stability, mechanical strength, and barrier properties. However, conventional bisphenol A-based resins and organic solvents may pose risks to reproductive, developmental, and immune systems, as well as contribute to atmospheric pollution. This mini-review critically evaluates recent advancements in fully waterborne bio-based epoxy nanocomposites as sustainable alternatives, with particular emphasis on their enhanced antibacterial and corrosion-resistant performance in tropical marine environments. A central focus is the role of chitosan-grafted graphene oxide (Chi-GO) as a multifunctional nanofiller that significantly enhances both antibacterial efficacy and barrier capabilities. For instance, coatings reinforced with Chi-GO exhibit up to two orders of magnitude lower corrosion current density than pristine epoxy coatings, and achieve over 95% bacterial inhibition against Escherichia coli and Staphylococcus aureus at a 1 wt.% loading. The review summarizes key synthesis methods, functional modification techniques, and commonly adopted evaluation approaches. Emerging research further underscores environmental performance metrics, including reduced volatile organic compound (VOC) emissions and improved life-cycle assessments. By integrating bio-based polymer matrices with Chi-GO, these composite systems present a promising pathway toward environmentally benign and durable protective coatings. Nevertheless, critical challenges concerning scalability and long-term stability under real-world operating conditions remain insufficiently addressed. Future research should emphasize scalable manufacturing strategies, such as roll-to-roll processing, and conduct extended tropical exposure testing (e.g., salt spray tests beyond 2000 h). Additionally, developing comprehensive life-cycle assessment (LCA) frameworks will be crucial for sustainable industrial implementation.
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是否译文:否
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发表时间:2025-11-06
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收录刊物:SCI
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李远哲
职务:Professor
主要任职:
个人信息
- 博士生导师
硕士生导师 - 教师英文名称:Yuanzhe
- 教师拼音名称:liyuanzhe
- 电子邮箱:
- 所在单位:碳中和研究院
- 职务:Professor
- 学历:博士研究生毕业
- 办公地点:中国矿业大学(文昌校区) 教三楼 碳中和研究院
- 性别:男
- 联系方式:yuanzhe.li@cumt.edu.cn
- 学位:哲学博士学位
- 毕业院校:Nanyang Technological University
学术荣誉:
- 2025当选:江苏特聘教授
曾获荣誉:
- 2023-12-27新加坡国家级范畴三(CSE3)半导体行业专家 & 碳税 主任审核员
- 2023-12-27新加坡经管局资源效率补助(REG(E))减碳项目 主任验证审核员
- 2025-11-11净零路径 (NetZero Pathway) 主任验证审核员
- 2025-02-28Verra 碳排放信用 VCS 主任审核员
- 2024-12-02碳中和 ISO14068认证 主任审核员
- 2024-11-27可持续性保证(ACSAP)认证资格 (AA1000注册)
- 2025-09-01ISO14067 产品碳认证 外部主任审核员
- 2024-03-04ISO14064 温室气体排放与碳核查 外部主任审核员(ANAB注册验证)
- 2025-10-01ISO50001 能源管理体系外部主任审员
- 2024-05-13ISO45001 职业健康安全管理体系外部主任审员 (CQI & IRCA注册)
- 2024-04-01ISO14001 环境管理体系 外部主任审核员 (CQI & IRCA注册)
- 2017-09-18新加坡人力部注册安全官(WSHO)
- 2025-09-01江苏特聘教授
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